Bromohydrin formation [Br2/H2O]

Bromohydrin Formation Definition:

Bromonydrin formation is addition reaction of Br and OH across the alkene and the product is called a bromohydrin (bromo=bromine, hydrin=hydro, water/H₂O).

Bạn đang xem: br2 + h2o

Bromohydrin Formation Explained:

Lewis acid lượt thích the bromine is able to lớn bond to lớn the alkene π electrons, and the resulting complex rearranges or is attacked by nucleophiles to lớn give addition products.

Xem thêm: na2so4 + ba(oh)2

The intermediate bromonium ion is a high-energy intermediate and will react with any nucleophile that it encounters. When water is the solvent, it is more likely that the bromonium ion will be captured by a water molecule before having a chance to react with a bromide ion. So water will add to lớn more substitute carbon by the S_N2 mechanism. This leads to lớn an anti-product and this means that will the bromine and the hydroxyl group will be on the opposite sides.